Ruthenium-ion-catalyzed oxidation of asphaltenes and oil-source correlation of heavy oils from the Lunnan and Tahe oilfields in the Tarim Basin, NW China     

马安来张水昌  张大江金之钧马晓娟  陈清棠 《中国地球化学学报》2005,24(1):28-36

The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields.  相似文献   

松辽、加西盆地非震地球物理预测稠油藏技术方法对比研究     

徐宝慈  王喜臣  贾建秀  尹航 《吉林大学学报(地球科学版)》2005,(Z1)

松辽盆地同加拿大西部盆地同属环太平洋构造带控制的中生代内陆盆地,二者在构造环境、演化条件等诸多方面有着许多相似之处。松辽盆地的稠油、油砂藏有着很可观的远景储量。借鉴加拿大地球物理勘探经验及技术,勘探并开发松辽盆地斜坡地带稠油、油砂藏。  相似文献   

利用地震属性研究准噶尔盆地西北缘拐19井区下侏罗统三工河组沉积环境   总被引：6，自引：0，他引：6       下载免费PDF全文

王世瑞  彭苏萍  凌云  王晓平  吴琳 《古地理学报》2005,7(2):169-184

在准噶尔盆地西北缘，寻找岩性圈闭油气藏已是至关重要的问题。但人们几乎还是用常规的手段来寻找岩性油气藏，没有实质性进展。本文是以利用宽方位角采集的地震数据为基础，对数据进行高保真资料处理和参考标准层的层拉平解释。利用前人的区域地质研究成果和钻井解释成果对侏罗系的沉积环境进行了精细的描述，确定了拐19井区在下侏罗统三工河组的出油层段附近的沉积环境由湖泊相－三角洲前缘相－河流相－湖泊相的演化过程。利用地震属性解释的结果也能较好地反映目标区的沉积环境变迁，并且与区域地质、测井解释结果相吻合，为寻找油气提供了很好的依据。由此得出利用地震属性可以进行沉积环境变迁分析，为油田寻找岩性圈闭及油气藏做出贡献。  相似文献   

Multi‐year water balance assessment of a newly constructed wetland,Fort McMurray,Alberta          下载免费PDF全文

Erin M. Nicholls  Sean K. Carey  Elyn R. Humphreys  M. Graham Clark  Gordon B. Drewitt 《水文研究》2016,30(16):2739-2753

Oil sands mining in Alberta transforms the boreal landscape of forests and wetlands into open pits, tailings ponds and overburden piles. Whereas reclamation efforts have primarily focused on upland forests, rebuilding wetland systems has recently become a motivation for research. Wetland creation and sustainability in this region is complicated by the sub‐humid climate and salinity of underlying mining material. In 2012, Syncrude Canada Ltd. completed the construction of the Sandhill Fen Watershed (SFW), a 52‐ha upland‐wetland system to evaluate wetland reclamation strategies on soft tailings. SFW includes an active pumping system, upland hummocks, a fen wetland and underdrains. To evaluate the influence of management practices on the hydrology of the system, this study reports the water balance from January 2013 to December 2014, the first 2 years after commissioning. A semi‐distributed approach was taken to examine the fluxes and stores of water in uplands and lowlands. Natural and artificial inputs and outputs were measured using a series of precipitation gauges and pumps, and evapotranspiration was quantified using three eddy covariance towers. A series of near surface wells recorded water table position. Both 2013 and 2014 were normal rainfall years, with 2013 having more and 2014 less snow than normal. In 2013, inflow/outflow from pumping was the predominant hydrological fluxes, resulting in considerable variability in water table position and storage changes throughout the summer. In 2014, the artificial addition of water was negligible, yet the water table remained near the surface in lowland locations, suggesting that wetland conditions could be maintained under current conditions. Evapotranspiration rates between uplands and lowlands were similar between years and sites, ranging from 2.2 ± 1.8 to 2.5 ± 1.2 mm/day and were largely controlled by climate. These rates were less than nearby older upland systems, suggesting that water balance partitioning will change as vegetation develops. Comparison between years and with natural systems provides insight on how management practices influence hydrologic dynamics and the overall water balance of the SFW. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Establishment and application of an intelligent treating method for oil spill identification     

TAN Liju  ZHAO Ruxiang  YIN Xiaonan  ZHANG Haijiang  WANG Jiangtao 《海洋学报(英文版)》2018,37(11):116-122

In the identifying process of an oil spill accident, manual integral and artificial visual comparison are commonly used at present to determine the oil spill sources, these methods are time-consuming and easily affected by human factors. Therefore, it is difficult to achieve the purpose of rapid identification of an oil spill accident. In this paper, an intelligent method of automatic recognition, integration and calculation of diagnostic ratio of Gas Chromatography-Mass Spectrometer (GC/MS) spectrum are established. Firstly, four hundreds of samples collected around the world were analyzed using a standard method and Retention time locking technology (RTL) was applied to reduce the change of retention time of GC/MS spectrum. Secondly, the automatic identification, integration of n-alkanes, biomarker compounds, polycyclic aromatic hydrocarbons and calculation of the diagnostic ratios were realized by MATLAB software. Finally, a database of oil fingerprints were established and applied successfully in a spill oil accident. Based on the new method and database, we could acquire the diagnostic ratios of an oil sample and find out the suspected oil within a few minutes. This method and database can improve the efficiency in spilled oil identification.  相似文献   

多极化SAR溢油探测影响因素分析研究     

宋莎莎  赵朝方  安伟  李晓峰  王臣 《海洋学报(英文版)》2018,37(11):77-87

Polarimetric synthetic aperture radar(SAR) oil spill detection parameters conformity coefficient(μ), Muller matrix parameters(|C|, B_0), the eigenvalues of simplified coherency matrix(λ_(nos)) and the influence of SAR observing parameters, ocean environment and noise level are investigated. Radarsat-2 data are used to make systematic analysis of polarimetric parameters for different incidences, wind speeds, noise levels and the ocean phenomena(oil slick and look likes). The influence of the SAR observing parameters, the ocean environment and the noise level on the typical polarimetric SAR parameter conformity coefficient has been analyzed. The results indicate that conformity coefficient cannot be simply used for oil spill detection, which represents the image signal to the noise level to some extent. When the signals are below the noise level for the oil slick and the look likes, the conformity coefficients are negative; while the signals above the noise level corresponds to positive conformity coefficients. For dark patches(low wind and biogenic slick) with the signal below the noise,polarization features such as conformity coefficient cannot separate them with oil slick. For the signal above the noise, the oil slick, the look likes(low wind and biogenic slick) and clean sea all have positive conformity coefficients, among which, the oil slick has the smallest conformity coefficient, the look likes the second, and the clean sea the largest value. For polarimetric SAR data oil spill detection, the noise plays a significant role. So the polarimetric SAR data oil spill detection should be carried out on the basis of noise consideration.  相似文献   

饲料中添加芽孢杆菌组分对凡纳滨对虾幼虾生长、能量代谢和抗WSSV能力的影响     

单洪伟  于鹏  刘宽  于明超  马甡 《中国海洋大学学报(自然科学版)》2020,(1):30-38

以凡纳滨对虾(Litopnnaus vannamei)幼虾为实验动物,在其基础饲料中分别添加芽孢杆菌(Bacillus sp.)胞外蛋白粗提物(1.0%,胞外蛋白组)、胞内多糖粗提物(1.0%,胞内多糖组),以基础饲料为对照组饲料,进行为期28d的养殖实验,探讨芽孢杆菌胞外蛋白和胞内多糖粗提物对幼虾生长、能量代谢及抗病能力的影响。研究表明,芽孢杆菌2种粗提物对凡纳滨对虾的生长和成活率影响不显著(P>0.05)。饲喂2种粗提物影响了凡纳滨对虾肝胰腺和肌肉中能量代谢相关酶活力。胞外蛋白组肝胰腺中磷酸果糖激酶(PFK)、乳酸脱氢酶(LDH)活力在养殖实验前期显著高于对照组(P<0.05),而肌肉中PFK、LDH活力显著低于对照组(P<0.05);胞内多糖组肝胰腺中己糖激酶(HK)活力及肌肉中PFK、LDH活力显著低于对照组(P<0.05)。饲喂2种粗提物均显著提高了凡纳滨对虾肌肉中琥珀酸脱氢酶(SDH)活力和肝胰腺中电子传递系统(ETS)活力(P<0.05),胞外蛋白粗提物对肝胰腺中的SDH活力也有显著的提高作用(P<0.05)。饲喂2种粗提物显著降低了凡纳滨对虾肝胰腺及肌肉组织中脂肪酸合酶(FAS)含量(P<0.05)。此外,饲喂2种粗提物均会显著提高凡纳滨对虾肠道蛋白酶活力(P<0.05),而胞外蛋白粗提物使凡纳滨对虾肠道脂肪酶活力显著降低(P<0.05)。白斑综合征病毒(WSSV)感染后,与对照组相比,胞外蛋白组和胞内多糖组凡纳滨对虾半致死时间分别延长了26.19%和7.14%。根据以上结果推测,芽苞杆菌2种粗提物能够影响凡纳滨对虾能量代谢水平并提高其抗WSSV能力,且二者之间密切相关。  相似文献   

Application of computational fluid dynamics simulation for submarine oil spill     

YANG Zhenglong  YU Jianxing  LI Zhigan  CHEN Haicheng  JIANG Meirong  CHEN Xi 《海洋学报(英文版)》2018,37(11):104-115

  相似文献   

胶州湾沉积物中石油降解菌的降解能力及多样性研究     

高伟  高祥兴  米铁柱  韩彬  张毅然  李馨子  尹晓斐  孙承君  李倩  崔志松  栾晓  于志刚  郑立 《海洋学报(英文版)》2019,38(6):54-64

2013年青岛输油管道爆炸，大量石油污染了附近海岸。课题组采集了污染的沉积物样品，以原油为唯一碳源和能源，富集了四个石油降解菌群。生物多样性和群落分析表明，Luteibacter、Parvibaculum 和属于食烷菌科的一个属是降解菌群的主要优势菌，都属于变形菌门。从石油降解菌群中分离筛选，获得了9株具有不同16S rRNA基因序列的降解菌，分别属于8个属。重量法测定降解菌的石油降解率，其中5株的石油降解率大于30%。GC-MS分析结果表明，石油降解菌多倾向于降解烷烃，对多环芳烃的降解能力较差，其中5株细菌的烷烃降解率较大，仅1株菌D2对多环芳烃的降解率较大，其降解率在34.9%到77.5%。通过对高通量数据的分析，表明食烷菌属是菌群A和菌群E的主要降解菌群，其中筛选获得的菌株E4可能是菌群E的一株优势降解菌。本研究所筛选菌株证明了其石油降解潜力，为油污染海滩生物修复提供了菌株资源。  相似文献   

南海北部海域油气勘探保障建设选址适宜性研究     

武二亮  陈浩东  刘裕光  安永宁 《海岸工程》2020,39(4):256-262

为分析南海北部海域油气勘探保障建设选址的适宜性,在广泛研究备选区特征资料的基础上,基于层次分析法(Analytic Hierarchy Process, AHP)原理,以自然环境因素、开发环境因素、基础设施与投资情况以及其他因素作为一级评判准则,建立了包括12项二级评判准则的递进层次结构模型,并以永兴岛、赵述岛和晋卿岛作为3个假定备选区,来验证分析评价模型的有效性和可靠性。AHP评判结果显示,3个备选区的整体优劣指数依次为0.587 1, 0.212 1, 0.200 8;AHP模型的一致性比例CR值为0.020 3。通过分析和筛选影响远海油气勘探保障建设的选址因子,构建基于AHP原理的选址评价模型,可用于分析评价南海北部岛礁油气勘探保障建设选址的适宜性。  相似文献